海洋溶解水蒸气吗?- 江南体育网页版- - - - -地球科学堆江南电子竞技平台栈交换 最近30从www.hoelymoley.com 2023 - 07 - 08 - t03:54:50z //www.hoelymoley.com/feeds/question/19238 https://creativecommons.org/licenses/by-sa/4.0/rdf //www.hoelymoley.com/q/19238 4 海洋溶解水蒸气吗? user18590 //www.hoelymoley.com/users/0 2020 - 02年- 17 - t20:09:31z 2020 - 02年- 21 - t00:10:52z < p >海洋溶解气体N <子> 2 < /订阅>或2 O <子> < /订阅>。< / p > < p > < a href = " https://en.wikipedia.org/wiki/Henry%27s_law " rel = " nofollow noreferrer " >亨利定律< / >建立之间有一个平衡的大气浓度气体及其浓度的海洋。< / p > < p >大气H <子> 2 < /订阅> O (g)。< / p > < p >有2 H <子> < /订阅> O (g)溶解在海洋或亨利定律并不适用,因为水也是2 H <子> < /订阅> O ? < / p > //www.hoelymoley.com/questions/19238/-/19243 # 19243 2 半日西蒙回答的海洋溶解水蒸气吗? 半日西蒙 //www.hoelymoley.com/users/39 2020 - 02年- 18 - t09:24:23z 2020 - 02年- 18 - t09:24:23z < p >我不是化学家,但是我准备上赌一把的答案是:< / p > < p >没有,没有水溶解在海洋里。水< em > < / em >海洋。< / p > //www.hoelymoley.com/questions/19238/-/19244 # 19244 2 回答trond汉森的海洋溶解水蒸气吗? trond汉森 //www.hoelymoley.com/users/6258 2020 - 02年- 18 - t14:46:52z 2020 - 02年- 18 - t14:57:16z < p >你那道问题的答案是“是”和“不是”。< / p > < p >你不会找到水溶解在水中,但水可以溶解的氧气,你可以找到在水中溶解氢在本质上我不知道它有多普遍,但在水中可以溶解氢。< / p > < p >,它看起来像氢化水是一个< a href = " https://en.wikipedia.org/wiki/Hydrogen_water " rel = " nofollow noreferrer " > https://en.wikipedia.org/wiki/Hydrogen_water < / > < / p > //www.hoelymoley.com/questions/19238/-/19245 # 19245 7 答案由M基海洋溶解水蒸气吗? 米的基 //www.hoelymoley.com/users/17518 2020 - 02年- 18 - t19:23:51z 2020 - 02年- 19 - t07:58:14z < p >答案是否定的,是的,也许,没有然后。< / p > < p > No:水蒸气不是“溶解”的海洋,而是成为海洋的一部分通过相变从蒸汽到液体(可能通过一个中间阶段作为冰)。“溶解”是指一种物质的过程中进入了一个“解决方案”,它被定义为稳定的混合物的两个或两个以上的物质状态的解决方案确定,一般来说,由溶剂(本例中的液态水)。例如,参见维基百科文章" < a href = " https://en.wikipedia.org/wiki/Solution " rel = " nofollow noreferrer " > < / >”。当水蒸气进入海洋,它只是增加了液体水的体积。水蒸气泡沫悬浮在海洋是另一个问题。气体溶解在液态时,它就不再是一种气体。所以我们没有“O2气体溶解在海洋,O2,气体在大气中,海洋中溶质。< / p > < p >是的:另一方面,有连续的大气和海洋之间的水交换:有时大气中的水通过海洋,有时反过来,这取决于天气状况。这是无事可做的过程是“溶解”,但是,如果问题是出于感兴趣的大气和海洋之间的物质交换,这两者之间循环的水,这是描述下面,将感兴趣的。

Finally, perhaps, no: the water vapour in the atmosphere is not in equilibrium with liquid water in the ocean (see wikipeadia foe discussion of equilibrium between liquid and gas phases). Generally speaking, the partial pressure of water vapour above the ocean will be below equilibrium, so there will be an evaporative flux of water from the ocean into the atmosphere. The steady evaporation of water from the surface of the oceans is balanced by precipitation (rain, sleet and snow) out of the atmosphere which falls on the oceans or falls on land and then drains into the oceans (see The Fundamentals of the Water Cycle).

//www.hoelymoley.com/questions/19238/-/19248 # 19248 5 答案由haresfur海洋溶解水蒸气吗? haresfur //www.hoelymoley.com/users/1242 2020 - 02年- 19 - t01:45:51z 2020 - 02年- 21 - t00:10:52z < p > TL;博士:亨利定律描述了一个理想的线性关系平衡的低浓度溶质在溶液中,溶质在气相的分压比的解决方案。拉乌尔定律描述理想的线性关系占主导地位的溶剂在溶液的浓度和溶剂的分压在上方的气体混合物。因为水是海洋的主要溶剂,亨利定律不适用。任何从大气中水蒸气溶解在海洋里简单地增加了溶剂。< / p > <人力资源> < p >亨利定律描述溶质在纯溶剂的行为。我将引用部分< a href = " https://en.wikipedia.org/wiki/Henry%27s_law " rel = " nofollow noreferrer " >你引用维基百科文章< / >将一些相关的点。< / p > < blockquote > < p >亨利定律是一个气体定律,指出溶解气体在液体的量正比于其分压高于液体。< / p > < /引用> < p >文章中被忽视的一点是,它假定不同气体的气相混合物是一种理想的——也就是说,他们遵循理想气体定律。这是一个非常好的近似地球大气层。对于理想气体,然后在溶液中浓度与空气中的浓度由亨利定律常数。常量的值取决于所使用的方程是书面和浓度单位。< / p > < blockquote > < p >亨利定律已被证明适用于广泛的溶质在无限稀释极限下(x→0),包括非易失性物质,如蔗糖。 In these cases, it is necessary to state the law in terms of chemical potentials. For a solute in an ideal dilute solution, the chemical potential depends only on the concentration. For non-ideal solutions, the activity coefficients of the components must be taken into account

Henry's law becomes exact at very low concentrations of the solute. At higher concentrations, there is deviation from ideality due to interactions between the dissolved species. This means Henry's law is only used for low-concentration solutes. At the other end, Raoult's law applies. So for H2O in the oceans the water is nearly pure so it behaves as an ideal liquid. In thermodynamic terms the ratio between the water partial pressure at equilibrium in air above the solution (the ocean) and the water partial pressure above pure water times the mole fraction of water in the ocean (the mole fraction is the number of moles of water divided by the total number of moles of the solution - so close to 1 because the ocean is mostly water).

If there was absolutely complete ideal mixing between two solutes, say ethanol and water, then Raoult's law would be followed for all mixtures between the two. This is the same as saying the Henry's law constant would be 1 if the concentrations are given in mole fractions. That is not usually the case and the slope of the linear Henry's law region is different. Here is a figure for ethanol water from a more rigorous answer to a question in chemistry stack exchange.

https://chemistry.stackexchange.com/questions/89872/what-are-the-key-differences-between-raoult-s-law-and-henry-s-law/90771

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