火星上的铁陨石为什么不生锈或氧化?为什么他们的?- 江南体育网页版- - - - -地球科学堆江南电子竞技平台栈交换 最近30从www.hoelymoley.com 2023 - 07 - 07 - t17:07:02z //www.hoelymoley.com/feeds/question/19515 https://creativecommons.org/licenses/by-sa/4.0/rdf //www.hoelymoley.com/q/19515 14 火星上的铁陨石为什么不生锈或氧化?为什么他们的? uhoh //www.hoelymoley.com/users/6031 2020 - 03 - 26 - t00:44:28z 2020 - 03 - 26 - t11:58:35z < p >维基百科维基百科的2005篇文章< a href = " https://en.wikinews.org/wiki/Mars_Rover%E2%80%99s_Basketball-Shaped_Discovery_Stirs_Controversy " rel = " noreferrer " >火星探测器的Basketball-Shaped发现激起争议< / >表示:< / p > < blockquote > < p >陨石的表面被发现明显的腐蚀。研究人员还不能确定这是否意味着它到达最近彻底或它可能是沙石。< / p > < /引用> < p >和链接到Space.com的< a href = " https://www.space.com/707-mars-rover-meteorite-discovery-triggers-questions.html " rel = " noreferrer " >火星探测器的陨石发现触发问题< / > < / p > < p >地球上我们通常不会看到干净、闪亮的铁表面,因为铁很容易在短时间内氧化甚至在室温下由几个氧化空气的组成部分。这些存在火星上当然在浓度低得多,但也有其他氧化剂包括< a href = " https://en.wikipedia.org/wiki/Perchlorate " rel = " noreferrer " >高氯酸盐< / >。然而铁陨石在火星上发现我知道的(< a href = " https://en.wikipedia.org/wiki/Heat_Shield_Rock " rel = " noreferrer " >隔热板岩< / >和< a href = " https://skyandtelescope.org/astronomy-blogs/astronomy-space-david-dickinson/curiosity-examines-iron-meteorite-egg-rock/ " rel = " noreferrer " >鸡蛋岩石< / >)看上去干净其他人所示,天空一样,望远镜的文章。< / p > < p >是知道为什么吗?最近他们降落,氧化没有多大变化,还是< em >喷砂清洁< / em > < a href = " https://en.wikipedia.org/wiki/Karen_Steele " rel = " noreferrer " >凯伦·斯蒂尔< / > ' s轨道前夕McHuron柯克告诉<年代> < / s >的一个矿工与一个肮脏的铸铁煎锅<一口> __ < /一口>第十二行星storm-plagued参宿七。< / p > < p >这两个陨石被好奇心的照片中可以看到< / p > < ul > <李> < a href = " https://astronomy.stackexchange.com/a/31815/7982 " >这个答案< / > < em >是什么名字的流星体撞击月球,火星,或者几乎任何不是地球?李李< / em > < / > < > < a href = " https://space.stackexchange.com/a/24660/12102 " >这个答案< / > < em >谁发现了“蛋摇滚”?好奇号还是人?< / em > < /李> < / ul > < p >也看到< a href = " https://mars.nasa.gov/resources/6433/curiosity-finds-iron-meteorite-on-mars/ " rel = " noreferrer " >好奇发现火星上的铁陨石< / > < / p > <人力资源> < p > <一口> __ < /一口> < a href = " https://scifi.stackexchange.com/a/229030/51174 " >这答案< / > < / p > < p > < a href = " https://i.stack.imgur.com/LT9h0.jpg " rel = " noreferrer " > < img src = " https://i.stack.imgur.com/LT9h0m.jpg " alt =“脏盘子上喷砂清洁storm-plagued第十二行星参宿七”。> < / > < / p > //www.hoelymoley.com/questions/19515/-/19516 # 19516 12 回答梧桐树下的铁陨石在火星上为什么不生锈或氧化?为什么他们的? 梧桐树下 //www.hoelymoley.com/users/18990 2020 - 03 - 26 - t02:00:08z 2020 - 03 - 26 - t11:58:35z < p > <强> tl; < /强>:博士与地球相比,火星大气中很薄;此外,它还含有更少的氧气和水(即。,很干)。冷得多。这些条件可能减缓氧化率无关。< / p > < p >纯铁的一个对象,注意根据英文维基百科关于< a href = " https://en.wikipedia.org/wiki/Mars气氛”rel = " noreferrer " >火星< / >:< / p > < blockquote > < p > "火星的大气层由约96%的二氧化碳、1.93%的氩气和1.89%的氮气与氧气和水的痕迹。”< / p > < /引用> < p >这贡献< em > < / em >合理贡献较小的氧化速度比地球上因为一个氧化剂的浓度(即。、氧气)低得多(0.146 %卷,根据表,< em >如上。< / em >)如果一个假设缺乏流程分裂< span class = " math-container " > $ \ ce{二氧化碳}$ < / span >产生氧气。设置这些值到上下文(条目< a href = " https://en.wikipedia.org/wiki/Earth气氛”rel = " noreferrer " > < / >)地球:< / p > < blockquote > < p > "干大气是由78.084%的氮、20.946%的氧气,氩气0.934%,微量的二氧化碳和其他气体分子。[…水蒸气含量在0.01%到4%之间变化但平均约为1%。" < / p > < /引用> < p >同样注意报道在火星表面温度(最小130 K, 210 K, max 308 K)大幅降低,比在地球上(最小184 K平均287.16 K,最大330 K)——同样< em > < / em >减缓氧化。< / p > < p >关于水和大气湿度:提供了陨石被水浸湿,说高氯酸盐可以作为氧化剂的铁开始工作。 In comparison to this, dry perchlorate will remain inactive. Again, Mars' atmosphere (0.0210 vol% of water vapour, ibid.) seems to be considerably more conservative than Earth's.

You can't have oxidation alone, it is a electrochemical process where some other material in contact with the one oxidized has to be reduced. Corrosion of the meteorites equally could occur if these simultaneously contain grains of metals / alloys differing in the their electrode potential provided

  • these grains were in close contact with each other, especially if their grain boundary were water wetted, and

  • if one of the metals / alloys -- relatively speaking -- would be «less noble», i.e. a material with a more negative reduction potential, than any other grain / material in contact. The less noble grain than would become a galvanic anode and eventually be "eaten away", protecting the other, more noble one, to be oxidized.(table) The formation of these little, local electrochemical cells could be even more important if there were salty water droplets on the surface at room temperature and above accelerating corrosion. (This, by the way, a reason why steel bridges and copper house roofs exposed to the climate and atmosphere of salty seas are more prone to galvanic corrosion than similar constructions only exposed to fresh water.) Presence of phosphates in said meteorites however could slow down the oxidation of the meteorites (passivation, as assumed for the Iron pillar in Dehli).

Note: The initial answer assumed iron meteorites to contain discrete grains, occasionally altogether with grains of other metals. A comment by@KenFabian pointed out iron meteorites however mainly consist of (Fe,Ni) alloys. Their electrochemical properties may be different to their components (e.g, table), which the edit aims to include.

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