有冰的核心,因为压力?- 江南体育网页版- - - - -地球科学堆江南电子竞技平台栈交换 最近30从www.hoelymoley.com 2023 - 04 - 16 - t08:37:19z //www.hoelymoley.com/feeds/question/20993 https://creativecommons.org/licenses/by-sa/4.0/rdf //www.hoelymoley.com/q/20993 4 有冰的核心,因为压力? 迟到的 //www.hoelymoley.com/users/21926 2021 - 03 - 22 - t17:13:54z 2021 - 03 - 29 - t19:21:57z < p >,因为有这么多的压力在地球的核心,核心是固体,但如果你能在内核中添加一些水或接近它。压力使水固体或蒸发吗?只做铁和镍在压力下将固体吗? < / p > //www.hoelymoley.com/questions/20993/-/20998 # 20998 7 Gimelist回答的可以有冰的核心,因为压力吗? Gimelist //www.hoelymoley.com/users/725 2021 - 03 - 24 - t13:02:24z 2021 - 03 - 24 - t13:02:24z < blockquote > < p >如果你设法在内核中添加一些水或接近它。< / p > < /引用> < p >它可能会与固态铁发生反应形成铁氢化(氧):< / p > < blockquote > < p >我们的观察表明,水很可能引入地球深处通过反应动力学和水的吸积和分离金属核心。此外,反应铁和水之间将发生在核心检测地幔边界,鉴于水释放含水俯冲板与金属相交的核心。挥发性高轴承自铁化合物的积累可能提供新的见解的神秘的抗震结构观察到下地幔的基地。< / p > < /引用> < p >(来源:< a href = " https://doi.org/10.1002/2017GL075720 " rel = " noreferrer " > https://doi.org/10.1002/2017GL075720 < / >) < / p > < p >换句话说,是否水冰,液体或蒸气non-question因为水分子2 H <子> < /订阅> O将不复存在。< / p > < p >你不需要的核心。带水,把它放在一块铁,和水会吸收铁生锈的形式:< span class = " math-container " > $ \ ce{铁0.5 + 0.5水+ o2 = FeOOH} $ < / span > < / p > < p >关于水的问题才会发生什么如果你想把它放在芯压力和温度,答案很简单:我们不知道。我认为没有人尝试实验。它可能不会是一个气体,压力太高了。熔点以来2 H <子> < /订阅> O比铁低得多,我想这将是一个液体。< / p > < p >的评论:< / p > < blockquote > < p > quora,他们说高压将冰的熔点较低,可能不如预期,使其蒸汽< / p > < /引用> < p >这仅仅是有关在相对较低的温度下,因为冰的晶体结构异常。 For most compounds, you need greater temperature to melt something which is at pressure. It's actually opposite for water, and closely related to the fact that ice floats on water (which is very counter-intuitive - usually solids are denser than liquids). But at high temperatures, of hundreds and thousands of degrees, water starts to behave normally under high pressure.

//www.hoelymoley.com/questions/20993/-/20999 # 20999 1 答案由Prasenjit Gorai有冰在请来的核心,因为压力? Prasenjit Gorai //www.hoelymoley.com/users/22092 2021 - 03 - 24 - t17:17:44z 2021 - 03 - 24 - t17:17:44z < p >找到这个问题的答案,我们需要回顾地球的形成过程的核心。简单地说,地球的分层结构密度分层的结果。密集的金属元素,不能形成复合物沉没到中心形成地球的核心。氢是最轻的元素,它几乎不会出现在地球的核心形成水。我们可以令人信服地说没有水在地球的核心,排除水的可能性存在固体,液体或蒸汽状态。< / p > < p >,如果我们假设水存在于核心。它将可能在超临界状态或形成复合物与其他金属的元素。< / p > //www.hoelymoley.com/questions/20993/-/21032 # 21032 5 奥斯卡Lanzi回答的可以有冰的核心,因为压力吗? 奥斯卡Lanzi //www.hoelymoley.com/users/20607 2021 - 03 - 29 - t01:20:14z 2021 - 03 - 29 - t19:21:57z

The answer is maybe -- if you are looking deep in the mantle rather than in the core, and if you are prepared to accept "superionic" ice in which the molecular structure of water has broken down and instead, you have mobile protons embedded in an oxide-ion lattice. In the core itself the water reacts with the hot iron under pressure, actually forming a metal hydride.

Fire and ice

Deep inside the Earth, where pressures reach GPa levels and temperatures exceed 2000 K, water may exist in two forms, neither of which is anything like the material we are familiar with at the surface. One of these is a supercritical fluid in which the temperature and pressure are not only too high to allow vapor-liquid equilibrium, but also high enough to turn the protons into highly mobile species in this fluid, which is therefore chock full of ionic species. The second of these forms is a "solid" in the sense that it contains a rigid lattice of oxide ions, but the hydrogen ions move among them as if they were still liquid. This is the long-sought and now (since 2019) verified superionic ice.

The University of Arizona [1] shows a calculated temperature-pressure relation as one proceeds deep into the Earth, given in the figure below.

enter image description here From Ref. [1].

The sharp rise in temperature in the middle of the chart corresponds to the boundary between the mantle and the core. We see that just short of this boundary the pressure is about 100 GPa and the temperature about 3000 K.

Under these conditions, some calculations such as that from Millot et al. [2] indicates that the water may turn into the superionic ice state at this boundary. In the figure below, the point at 100 GPa and 3000 K lies in the white border region where, according to the authors' calculations, the water may be an ionic supercritical fluid or superionic ice. At lower depths, however, the temperature and pressure are more firmly in the green ionic fluid range.

enter image description here From Ref. [2]. Figure link

And then there was none

Water vapor is well known to react with iron and steel in industrial processes, forming iron oxide and hydrogen (we usually limit the water vapor content and add hydrogen to the atmosphere to halt this reaction). Such a reaction also occurs under the high pressure and temperature of the core [3], although it takes a different course. Instead of evolving as gas, the hydrogen from the water forms a layer of iron hydride, a material which, as a pure compound, is unstable under normal conditions. This acts as a source of hydrogen that may reduce material in the overlying mantle. See the figure below.

From Ref. [3]. Figure sourceenter image description here

References

1. Educational material from the University of Arizona.

2. Marius Millot, Federica Coppari, J. Ryan Rygg, Antonio Correa Barrios, Sebastien Hamel, Damian C Swift, J. H. Eggert, "Nanosecond X-ray diffraction of shock-compressed superionic water ice", Nature 569(7755):251-255 (May 2019). DOI: 10.1038/s41586-019-1114-6

3. Ho-Kwang Mao, Qingyang Hu, Liuxiang Yang, Jin Liu, Duck Young Kim, Yuanku Meng, Li Zhang, Vitali B. Prakapenka, Wenge Yang, Wendy L. Mao, "When water meets iron at Earth's core mantle boundary", National Science Review 4(6), 109 (Sept. 2017). DOI: 10.1093/nsr/nwx109

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