从地下深处当钻石“迁移”到表面,他们维持压力在外面当没有更多的压力?如果是这样,如何?- 江南体育网页版- - - - -地球科学堆江南电子竞技平台栈交换 最近30从www.hoelymoley.com 2023 - 03 - 25 - t16:03:10z //www.hoelymoley.com/feeds/question/23132 https://creativecommons.org/licenses/by-sa/4.0/rdf //www.hoelymoley.com/q/23132 6 从地下深处当钻石“迁移”到表面,他们维持压力在外面当没有更多的压力?如果是这样,如何? uhoh //www.hoelymoley.com/users/6031 2021 - 11 - 12 - t00:10:29z 2023 - 01 - 23 t23:13:10z < p >从科学新闻的< a href = " https://www.sciencenews.org/article/mineral-diamond-davemaoite-earth-mantle-heat " rel = " noreferrer " >一种矿物中发现钻石的缺陷包含地球的热量的来源< / >:< / p > < blockquote > < p >一点点的岩石被困在一个钻石现在打开一个全新的窗口进入地球的下地幔是什么样子。在钻石是一个< a href = " https://www.sciencenews.org/article/mineral-diamond-davemaoite-earth-mantle-heat: % 7 e:文本=新% 20确定% 20硅酸盐% 20矿物% 20名为% 20 davemaoite”rel = " noreferrer " >新发现硅酸盐矿物称为davemaoite < / >,只能形成于地球的下地幔,研究人员报道11月12日的《科学》上。这是第一次,科学家们已经明确证明这种类型的下地幔矿物——以前刚从实验室实验预测——实际上存在于自然。团队< a href = " https://www.sciencenews.org/article/flaws-make-it-geologists-best-friend " rel = " noreferrer " >命名的矿物< / >著名实验高压地球物理学家Ho-kwang (Dave)毛(SN: 3/16/04) < / p > < /引用> < blockquote > < p >科学家此前估计,约5%至7%的下地幔必须由矿物,Tschauner说。但这是极其难以直接观察到这种deep-Earth矿物质。因为稳定的矿物在激烈的压力下地幔的——延伸到地球表面2700公里以下——<强>开始尽快重新安排他们的晶体结构允许的压力。< /强> < / p > < /引用> < blockquote > < p >甚至地球上最常见的矿物,< a href = " https://www.sciencenews.org/article/earths-most-abundant-mineral-finally-has-name " rel = " noreferrer " >下地幔镁铁硅酸盐称为bridgmanite < / >,主要是理论直到2014年,当它被发现有自然发生在澳大利亚陨石撞击的力量产生破碎、岩石的深mantle-like压力(SN: 11/27/14)。迄今为止,bridgmanite是唯一的其他高压硅酸盐矿物证实存在于自然。< / p > < /引用> < blockquote > < p > <强>钻石像时间胶囊,锁定在原始矿物形式表面上他们的旅程。< / >强davemaoite的发现不仅是确认它的存在,但它也揭示了地球深处的热源的位置.... By identifying the chemical makeup of davemaoite, researchers can now confirm where those elements reside.

That’s because the Botswana diamond also contained a high-pressure form of ice as well as another high-pressure mineral known as wüstite (SN: 3/8/18). The presence of those inclusions helped narrow down the rough pressures at which the davemaoite might have formed: somewhere between 24 billion pascals and 35 billion pascals, Tschauner says. It’s hard to say exactly what depth that corresponds to, he adds. But the discovery directly links heat generation (the radioactive materials), the water cycle (the ice) and the carbon cycle (represented by the formation of the diamond itself), all in the deep mantle, Tschauner says.

From the article I think that I'm being told that the diamond is preserving enough pressure to keep both the "davemaoite" and " a high-pressure form of ice" and the wüstite stable as well.

Am I understanding this correctly?

Question: When diamonds "migrate" from deep underground to the surface, do they maintain pressure inside when there is no more pressure outside? If so, how?

I would think that as the diamond rises to the surface and the pressure relaxes outside it would relax and expand uniformly and the pressure would relax inside as well. If that's not the case, why not?


The tiny gray blobs of mineral embedded in this slice of clear diamond are the first samples of newly named davemaoite, a calcium silicate perovskite mineral that only forms in the lower mantle. AARON CELESTIAN/NATURAL HISTORY MUSEUM OF LOS ANGELES COUNTY

The tiny gray blobs of mineral embedded in this slice of clear diamond are the first samples of newly named davemaoite, a calcium silicate perovskite mineral that only forms in the lower mantle. AARON CELESTIAN/NATURAL HISTORY MUSEUM OF LOS ANGELES COUNTY

//www.hoelymoley.com/questions/23132/-/23153 # 23153 4 答案由托马斯·佩里当钻石从地下深处“迁移”到表面,他们维持压力在外面当没有更多的压力?如果是这样,如何? 托马斯·佩里 //www.hoelymoley.com/users/24857 2021 - 11 - 14 - t04:30:05z 2021 - 11 - 14 - t04:30:05z < p >问题是关于压力的罕见,地幔矿物形成可见的在一个钻石包容。金刚石晶体内的夹杂物的压力真的是限制碳的晶体晶格内的压力,使钻石是什么。我们跑题了一会儿。< / p > < p >钻石是共价晶体。每个碳原子的钻石水晶被绑定到四个碳原子的四面体地取向,从而形成一个正四面体和一个碳原子在中心,分别在四个顶点,每个原子共享< em > < / em >电子在一个共价键。这种共价晶体结构呈现钻石晶体作为一个分子。在天然矿物质,共价键也呈现钻石极其困难。因此,晶体结构是非常困难的脱臼或剪切,将打破,或骨折,因此。这个特征应该与替代晶形碳相比,即石墨。我们都知道,石墨是极其容易剪切和休息。 Without graphite, we would be without pencils.

Diamond crystals form at extraordinarily high temperatures and pressures deep within the earth's upper mantle. Nevertheless, the diamond crystal is unstable at temperatures and pressures where graphite is stable. The crystalline structure of diamond has unsatisfied bonding abilities on its crystal surface as the crystal-bonding elements there are not surrounded by other covalent bonding units. At the earth's surface, the crystal will reactively degenerate into graphite at a formidably slow rate, but will not readily oxidize unless by forced ignition. However, these extraordinarily strong covalent bonds result in an extremely high packing density of carbon atoms, and thereby also prevent the crystalline structure from alteration due to pressures existing where the crystal is unstable. Apparently there is little or no alteration in the dimensional stability of the crystalline structure of diamond due to changes in pressure. In other words, the dimensional stability of diamond is not sensitive to changes in pressure. Diamond cannot be compressed.

Inclusions of other minerals within the diamond crystal are rarely formed at the same pressure and temperature conditions under which the diamond was formed. These mineral inclusions are formed some considerable time before formation of the diamond and under conditions even more extreme. An inclusion is simply a formational artifact or otherwise a crystal of some other mineral contained within the diamond crystal. Inclusions may be typically small. Predominantly formational for gem-quality diamonds, these inclusions are graphite, or otherwise crystalline twinning of the diamond caused by irregularities in the crystal structure as the diamond was formed. But in some rare cases, these inclusions are of crystalline minerals that formed in deep time considerably before formation of the diamond, and at more extreme pressures deep within the mantle. Such inclusions may predate the formation of the diamond by billions of years. In other words, when the diamond crystal formed, it grew around this type of mineral inclusion.

As we can see, some diamonds may have a history that is very interesting. In particular regarding the present question, the small inclusions of davemaoite crystals would not exist at the earth's surface if not for the confining pressure formed consequent to the diamond's crystalline lattice of densely packed, covalently-bound carbon atoms. Recall that the crystalline structure of diamond is extraordinarily difficult to dislocate or shear, and the packing of carbon atoms in the crystal lattice is extraordinarily dense. Consequently, each davemaoite inclusion was trapped within the diamond crystal as the crystalline lattice grew around the inclusion. The unique crystalline covalent bonding structure of the diamond, itself, confines the davemaoite crystals at extreme pressure.

//www.hoelymoley.com/questions/23132/-/23525 # 23525 3 回答时,奥斯卡Lanzi钻石从地下深处“迁移”到表面,他们维持压力在外面当没有更多的压力?如果是这样,如何? 奥斯卡Lanzi //www.hoelymoley.com/users/20607 2022 - 02年- 13 - t17:47:28z 2023 - 01 - 23 t23:13:10z < p >的一个更有趣的例子钻石维护其晶格中讨论高压< a href = " https://space.stackexchange.com/questions/18374/what-forms-of-water-ice-have-been-observed-and-verified-in-the-solar-system/33570 # 33570 " >这个答案< / >从太空探索。第七把短暂,冰夹杂物中发现了钻石在地球表面尽管这个阶段的水需要GPa压力水平。在这种情况下所需的压力一定是继承了在金刚石晶格内发现了冰,和晶格参数的计算压力确实是8 - 11 GPa之间冰七世将是稳定的。< / p > < p >倾向于保持内部压力并不完全独特的钻石。任何固体形成的压力下能够保持这样的压力在其晶格内部。然而,如果周围的压力释放后,材料也会变形,以减轻内部压力。大致上,只有一个类似数量的压力屈服强度(通常是远低于体积弹性模量)预计将被保留。这背后的力学结果描述如下。For most solids this limit is so low that the inclusions end up in their "normal" low-pressure phases, not very interesting. What is unique about diamond is its much superior strength: [Ruoff1](https://doi.org/10.1063/1.326378) gives a yield strength of 35 GPa, enabling it to rentain enough internal pressure (if it is formed under such pressure) to stabilize Ice VII, perovskite-structured silicates, etc.

Reference

Arthur L. Ruoff (1979). "On the yield strength of diamond". Journal of Applied Physics 50, 3354. https://doi.org/10.1063/1.326378


The pressure's on: How a solid matrix retains pressure ... or not

Consider a spherical particle of radius $r_p$ exerting pressure $P$ on a surrounding solid matrix. In the absence of a counterbalancing pressure from the outside, the imposed pressure from within generates a compressive stress $\sigma_c$ in the radial direction and a tensile stress $\sigma_t$ in the two orthogonal directions (along spheres concentric with the particle) through the volune of the surrounding solid. As shown in the picture below, both components decrease with the cube of the distance from the particle, and so have maximum magnitude at the particle surface. There the negative compressive stress is $-P$ and the positive tensile stress is $+P/2$.

enter image description here

We can apply the Von Mises yield criterion which states that the surrounding matrix yields, thus reducing the retained pressure, when

$(\sigma_1-\sigma_2)^2+(\sigma_2-\sigma_3)^2+(\sigma_3-\sigma_1)^2\ge2(YS)^2$

where $\sigma_1,\sigma_2,\sigma_3$ are the three orthogonal principal components of the stress tensor. Here $\sigma_1=\sigma_c=-P$ and $\sigma_2=\sigma_3=\sigma_t=+P/2$, from which the yield criterion then becomes

$P\ge(2/3)(YS)$

For a diamond lattice with a yield strength of 35 GPa this means the diamond can sustain a pressure up to 23 GPa, as quoted in the main text, around an Ice VII inclusions, whereas most other minerals would have yield stresses well below 1 GPa and thus fail to retain enough pressure to sustain Ice VII or other GPa-pressure phase inclusions.

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